Temperature Effects on the Crystalline Structure of iPP Containing Different Solvent-Treated TMB-5 Nucleating Agents.

Abstract

TMB-5 nucleating agent (NA) treated by different solvents were used as the β-NA of iPP. The effects of temperature on the crystalline structure of different iPP/TMB-5, as well as the crystallization and melting behaviors were investigated. It was found that strong polar solvent treated TMB-5 (TMB-5DMSO and TMB-5DMF) could induce more β-crystal at high Tc = 140 °C than the other TMB-5 NAs, while the β-crystal inducing efficiency of untreated TMB-5 (TMB-5UT) and non-polar solvent treated TMB-5 (TMB-5LP) is seriously reduced at high Tc = 140 °C. TMB-5DMSO can induce a high and stable content of β-crystal with Kβ = 83-94% within Tc = 90-140 °C, and TMB-5ODCB can induce a high content of β-crystal with Kβ > 91.3% within Tc = 90-130 °C. TMB-5DMF is the most temperature-sensitive one, but can induce a high fraction of β-crystal with Kβ > 92% both at low Tc = 90 °C and high Tc = 140 °C. High temperature pre-crystallization at Tpc = 150 °C tremendously reduces the β-crystal inducing efficiency of all TMB-5 NAs. TMB-5UT and TMB-5LP exhibit higher nucleating efficiency than TMB-5DMSO, TMB-5DMF and TMB-5ODCB. During the non-isothermal crystallization process, TMB-5UT induced β-crystal possesses higher structural perfection and stability, while TMB-5LP is more likely to induce α-crystal with considerable quantity and stability. The structural perfection and stability of TMB-5 induced β-crystal can be enhanced with appropriate increasing of Tc.