Abstract

The synthesis and emissive properties of bichromophoric molecules are reported. All systems contain an anilino group as a one-electron donor (D) and various substituted ethylene moieties as electron acceptor (A) separated by a rod-shaped alicyclic framework provide by a piperidine ring. From the emissive properties it is concluded that in these molecules the electronic coupling between D and A is sufficient to allow complete charge transfer upon excitation (if thermodynamically feasible)

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