Abstract
Abstract A rhodium complex Rh 2 (OAc) 4 catalyzed the reaction of nitrobenzenes and diphenylphosphine oxide HP( O)Ph 2 giving o -(diphenylphosphinoyloxy)anilines predominantly, which were accompanied by small amounts of the p -isomers. Nitorobenzenes possessing a bulky o -substituent, particularly o -( t -butyl)nitrobenzenes, underwent the reaction in high yields. The reaction is considered to involve the reductive formation of O -phosphinoyl- N -arylhydroxyamines from nitrobenzenes, and o -phosphinoyloxylation by the rearrangement.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
