Abstract
A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.
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