Abstract

Сatalytic direct phosphonation of aromatic C(sp2)-H bonds electrochemically induced were realized for the synthesis of diphenylphosphine oxide derivatives. Electrochemical pathway to CH/PH cross-coupling of phenylacetylene and diphenylphosphine oxide has been performed. The bisphosphine oxide and target diphenyl(phenylethynyl)phosphine oxide were obtained with mild to high yield.

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