Synthesis of NaA zeolite membranes from clear solution

Abstract

NaA zeolite membranes were successfully synthesized on a porous α-Al 2O 3 support from clear solution. The synthesis parameters, such as surface seeding, synthesis time, synthesis stages, etc. were investigated. Surface seeding can not only accelerate the formation of NaA zeolite on the support surface, but can also inhibit the transformation of NaA zeolite into other types of zeolites. A continuous NaA zeolite membrane formed on the seeded support after 2 h of synthesis. Gas permeation results showed that a synthesis time of 3 h produced the best NaA zeolite membrane. When the synthesis time was longer than 4 h, the NaA zeolite on the support surface began to transform into other types of zeolites, and the quality of the NaA zeolite membrane decreased. The quality of the NaA zeolite membrane can be improved by employing the multi-stage synthesis method. The NaA zeolite membrane with a synthesis time of 2 h after a two-stage synthesis showed the best gas permeation performance. The permeances of H 2, O 2, N 2, and n-C 4H 10 decreased as the molecular kinetic diameter of the gases increased, which showed the molecular sieving effect of the NaA zeolite membrane. The permselectivities of H 2/ n-C 4H 10 and O 2/N 2 were 19.1 and 1.8, respectively. These values are higher than the Knudsen diffusion ratios of 5.39 and 0.94. However, the permeation of n-C 4H 10 also indicated that the NaA zeolite membrane had certain defects with diameters larger than the pore size of NaA zeolite. A synthesis model was proposed to clarify the effect of surface seeding.