Synthesis of NaA and NaX Zeolite Membranes by Fumed Silica Via Clear Solution Gel

Abstract

NaA zeolite membranes have been used for dehydration of organic solvents in laboratory and commercial scales. There are many synthesis methods and conditions for manufacturing the membranes. The use of lactescent and clear gel solutions are two of the most important choices for high quality hydrothermal synthesis of NaA zeolite membrane in gas separation or dehydration of organic solvents. In this article, effect of hydrothermal synthesis time was investigated using the clear gel solution (Al2O3:5SiO2:50Na2O:1000H2O). Phase transformation from NaA to NaX was recognized as the most possible event when the clear gel solution was used. XRD spectra, SEM images, and GC analyses were used for evaluation of zeolite crystal phase, the membrane layer quality, and the contents of organic substances (ethanol or 2-propanol) in feed and permeate streams in pervaporation tests, respectively. From synthesis of zeolite membrane at different times, it was revealed that for achieving the pure NaA zeolite phase the synthesis time should not exceed 3 h at 100°C.