Abstract
Herein, we report the synthesis of 2,3-unsaturated carbazolyl and 3,3′-bicarbazolyl aldehydes by a Heck coupling methodology and the further condensation of these aldehydes with N-methyl-N-phenylhydrazine and N,N-diphenylhydrazine, resulting in mono- and dihydrazones that act as effective hole transporting materials. The thermal, optical and photophysical properties of the newly synthesized organic electroactive derivatives have been investigated. Room temperature hole-drift mobility values ranged from 10−4 to 10−3cm2/Vs in strong electric fields. The ionization potentials (Ip) of the investigated compounds were very close and ranged from 5.15 to 5.28eV, which can be attributed to a very weak conjugation of the carbazole segments of the 3,3′-bicarbazolyl moiety of the synthesized dihydrazones.
Published Version
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