Abstract
This article describes the preparation and characterization of cis-[Ru(bipy)2L](ClO4)2 and trans-[RuCl2L2] · Cl (bipy = 2,2′-bipyridyl and L = ortho-phenylenediamine (o-phd), 2-aminopyridine (2-apy) and 2-aminobenzonitrile (2-abn), and examines the catalytic oxidations of benzyl alcohol, benzohydrol and pipronyl alcohol by cis-[Ru(bipy)2 (o-phd)](ClO4)2 and trans-[RuCl2(o-phd)2] · Cl complexes at room temperature and in the presence of N-methyl morpholine-N-oxide (NMO) as co-oxidant.
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