Abstract
A new 3d–4f heterometallic coordination polymer: [MnIIGd2III(OAc)8(H2O)4]·6H2O (1) (OAc−=acetate), has been conventionally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. In 1, two Gd3+ and one Mn2+ cations are linked by carboxylic bridge of OAc− anions, giving a 1D 3d–4f heterometallic [MnIINd2III(OAc)8(H2O)4] chain. In the chain, there exist the short distances between the adjacent Gd(III) and Mn(II) ions as well as Gd(III) and Gd(III) ions, which make this 1D polymer displaying interesting magnetic properties.
Published Version
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