Abstract
A pair of novel azido-bridged polynuclear zinc(II) complexes, [Zn2(L1)2(μ1,1-N3)2]n (1) and [Zn2(L2)2(μ1,1-N3)(μ1,3-N3)] n (2) (HL1 = 2,4-dichloro-6-[(2-ethylaminoethylimino)methyl]phenol, HL2 = 2-bromo-4-chloro-6-[(2-ethylaminoethylimino)methyl]phenol), have been synthesized and structurally characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. Each zinc(II) atom in the complexes is in a trigonal-bipyramidal coordination, with one imine N atom of a Schiff base ligand and two N atoms from two bridging azide ligands defining the basal plane, and one phenolate O and one amine N atoms of the Schiff base ligand occupying the two axial positions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
