Abstract
Abstract[Pb(phe)2]n (1) (phe is the abbreviation ofphenylalanine) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. The single crystal structure of 1 show the complex to be a 2D chain polymer as a result of phenylalanine bridging. Coordination number of PbII ions is six, PbN2O4, with “stereo‐chemically active” electron lone pairs, and the coordination sphere is hemidirected. To the best of our knowledge, this 2D coordination polymer is the first amino acid lead(II) complex that characterized by X‐ray structural analysis.
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