Abstract
AbstractThe compound {[Pb(PDT)4][PbBr3]2}n (1) (PDT = 3‐(2‐pyridyl)‐5,6‐diphenyl‐1,2,4‐triazine) was synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy and thermal gravimetric analysis. The crystal structure of 1 showsthat the compound consists of a cationic lead(II) complex, [Pb(PDT)4]2+, and an anionic lead(II) 1D coordination polymer, [(PbBr3)–]n. The coordination numbers of PbII in cationic complexes and anionic polymers are eight for PbN8, and six for PbBr6, respectively, with “stereo‐chemically inactive” electron lone pairs, and the coordination spheres are holodirected. To the best of our knowledge, this compound is the first example of the aggregation of a discrete cationic lead(II) complex with an anionic 1D bromoplumbate coordination polymer that was characterized by X‐ray structural analysis.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
