Sustained arc temperature: better marker for phase transformation of carbon black to multiwalled carbon nanotubes in arc discharge method

Abstract

The present study investigates the role of temperature in the formation of multiwalled carbon nanotubes from carbon black using arc discharge technique. Carbon black has been used as precursor to synthesize carbon nanotubes in argon atmosphere. The arc current has been varied from 25 to 40 A in order to study the morphological changes in carbon black as it gets converted to multi walled carbon nanotubes (MWCNTs). We observed formation of MWCNTs at an arc current of 25 A; however the recorded temperature data suggested correlation of sustained arc temperature with the nanotube formation rather than the magnitude of current in its absoluteness. Interesting to note is that reported current magnitude in published literature are very high (>40 A) for conversion of carbon black but the present investigation shows that it is possible to convert the carbon black to MWCNTs even at lower current values in case the arc temperature is stabilized and sustained for longer period. Detailed investigations suggested that a sustained stable critical temperature of 1400 °C–1600 °C is essential for the growth of nanotubes and an unstable arc causing temperature fluctuation from critical temperature value yields very low or no MWCNTs.