Effect of Magnetic Field on the Growth of Aligned Carbon Nanotubes Using a Metal Free Arc Discharge Method and their Purification

Abstract

Multiwalled Carbon Nanotubes (MWCNTs) have been synthesized using a low cost arc discharge method without using metal catalyst and vacuum devices. Effect of magnetic field on the synthesis of MWCNTs and their purity has been scrutinized. A magnetic field of 310 gauss has been found to give better purity of carbon nanotubes as confirmed by Raman spectroscopy. However, the removal of amorphous carbon from the surface of so prepared multiwalled carbon nanotubes has been achieved by different oxidizing conditions. It has been observed that the maximum removal of amorphous carbon found by using the strong oxidizing agent HNO3/H2O2. This strong oxidizing agent HNO3/H2O2removes most of the carbonaceous impurities leading to thermal stability of carbon nanotubes suggested by thermo gravimetric analysis. X-ray diffraction show the formation of carbon nanotubes having a peak indexed at (002) as the fingerprint for multiwalled carbon nanotubes. Fourier Transform Infrared (FTIR) spectra confirmed the formation of the multiwalled carbon nanotubes showing a characteristic stretching band at 1615 cm-1corresponding to the C=C bonds of tubular carbon. Raman spectroscopy revealed invaluable insights into the purification of nanotubes. G-band (1577 cm-1) corresponds to the confirmation of MWCNTs. Defect induced D-band (1355 cm-1) has been minimized after purifying CNTs with HNO3/H2O2for 24 hrs. Transmission Electron microscopic (TEM) studies indicate the formation of CNTs with controlled alignment having diameter in the range 2-8 nm.