Abstract
Three substituted carbenes, nitrene, and two substituted nitrenes generated by pyrolysis of the appropriate precursors are shown to irreversibly modify the surface of stainless steel. Critical surface tension values obtained from wettability measurements are used to establish the presence of the various reacted species on the stainless steel surface. The infrared frustrated multiple internal reflection spectrum of the difluorocarbene modified stainless steel surface is used to establish that a sigma-diadsorbed-olefin complex may be formed on the metal surface.
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