Abstract

A flexible piezoelectric nanogenerator (PENG) was developed to convert ambient mechanical energy into electrical energy. Highly crystalline template-free zinc oxide (ZnO) microrods were prepared using a wet chemical method at a low temperature. As-synthesized ZnO microrods were blended with polyvinylidene fluoride (PVDF) to prepare a piezoelectric composite film using the supersonic spraying method. A PENG electrode comprising ZnO microrods (0.5 g) produced 15.2 V under a tapping force of 20 N at 5 Hz. In addition, an output current of 32 μA was produced with a maximum power density of 12.5 μW cm–2. The output voltage considering various body movements was investigated to demonstrate the flexibility and durability of the proposed PENG. Furthermore, the supercapacitive properties of ZnO/reduced graphene oxide were studied.

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