Abstract

A series of compounds R2CaBa2Cu5Oz (R=La, Pr, Nd and Eu) have been synthesized by conventional solid state reaction and characterized for their structural, superconducting and magnetic properties. All compounds crystallize with the tetragonal LaBa2Cu3Oz type structure, space group P4/mmm. Among the four compounds studied here, R=La, Nd and Eu are superconductors with superconducting transition temperatures (TcR=0) of 72, 40 and 55 K, respectively. On the other hand, neither superconductivity nor magnetic ordering is seen for R=Pr down to 3 K. The effect of the magnetic field on the susceptibility and (magneto) resistance for the superconducting samples has been investigated. The superconductivity of compounds with magnetic rare-earth ions Nd and Eu exhibit a profound influence of the magnetic field, whereas the application of the magnetic field has a limited effect on the La compound. The Pr compound is paramagnetic and does not exhibit magnetic ordering either.

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