Octahedral tilting and emergence of ferrimagnetism in cobalt-ruthenium based double perovskites

Abstract

Rare earth based cobalt-ruthenium double perovskites A2CoRuO6 (A = La, Pr, Nd and Sm) were synthesized and investigated for their structural and magnetic properties. All the compounds crystallize in the monoclinic P21/n structure with the indication of antisite disorder between Co and Ru sites. While La compound is already reported to have an antiferromagnetic state below 27 K, the Pr, Nd and Sm systems are found to be ferrimagnetic below , 55 and 78 K respectively. Field-dependent magnetization data indicate prominent hysteresis loop below in the samples containing magnetic rare-earth ions, however, magnetization does not saturate even at the highest applied fields. Our structural analysis indicates strong distortion in the Co–O–Ru bond angle, as La3+ is replaced by smaller rare-earth ions such as Pr3+ , Nd3+ , and Sm3+ . The observed ferrimagnetism is possibly associated with the enhanced antiferromagnetic superexchange interaction in the Co–O–Ru pathway due to bond bending. The Pr, Nd and Sm samples also show the small magnetocaloric effect with the Nd sample showing the highest value of magnitude ∼3 J kg−1K−1 at 50 kOe. The change in entropy below 20 K is found to be positive in the Sm sample as compared to the negative value in the Nd counterpart.