Abstract
The spin-label method was used for a study of the steric organization of the linear polyethyleneimine (PEI) macromolecules in glassy water-alcohol solutions in the course of complex formation with transition metal ions. The average local density of PEI chain units was measured, as well as PEI coil volume and the average distance spin-labels. In the case of complexes formed between the spin-labeled PEI and the Cu(II), Ni(II) and Co(II) ions the average distances between a label and the nearest paramagnetic complexes were determined experimentally. The average local concentrations of complexes in the PEI coil volume calculated from the data on their interaction with labels were found to be underestimated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
