Abstract
The spin-lattice relaxation mechanism based on the energy modulation of spin-orbital interaction has been investigated in the triplet excited states of impurity molecular crystals. This modulation emerges as a result of the admixture of the rotational motions of a molecule and the vibrational motions of nuclei to the translational molecular motions at the acoustic lattice vibrations. In the framework of this spin-lattice relaxation mechanism the direct one-phonon processes are studied at low temperatures and in high magnetic fields. The calculations of angular, field and temperature dependences of the spin-lattice relaxation rates for a real deuterobenzophenone crystal with an isotopic impurity were carried out using the molecular oribital and atom-atom potential methods.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
