Abstract
The morphology and structure of the mesophase in the series: coal tar pitch (CTP) - α-fraction of CTP - carbonised α-fraction after heating to 1200 °C, were studied by scanning electron microscopy, X-ray phase and X-ray structural analysis. The X-ray structural parameters were determined: longitudinal and transverse dimensions of the lamellae and the thickness of packages, the distance between the lamellae and the number of lamellae in the formed packages. It is shown that the two-dimensional structures of carbon mesophase are ordered into three-dimensional packages during the formation of semi-coke under CTP heating. It is established that the carbon structure of CTP and its α-fraction is represented by the turbostratic and graphite-like phases. The sizes of the packages formed by the lamellae during structuring in the transverse direction in the studied samples are of the order of 18-25 Å, in the longitudinal direction 46-63 Å, the average distance between the lamellae in the studied samples is 3.46-3.52 Å.
Published Version
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