Abstract

Reaction of the dicarbollide ions (3)-1,2- and 1,7-B 9C 2H 11 2− with the acetylacetonates of Zr(IV) and Hf(IV) gave (3)-1,2- and 1,7-B 9C 2H 12 − salts of M 4(acac) 4(OH) 11 +. The cation is The cation is formulated as a hydroxyl bridged species with terminal acetylacetonate groups.

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