Abstract
Combined Mössbauer and vibrational spectroscopic investigations revealed the presence of three structural units in the bis-terpyridine-iridium(III) complex in the solid state. A similar investigation of mixed o-phenanthroline halide complexes of iridium(III) indicated that the procedures elaborated to synthesize the cis and trans isomers of these complexes in fact led to the same product, the cisisomer.
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