Abstract
Polyvinyl alcohol (PVA) films doped with 10[Formula: see text]wt.% of yttrium chloride (YCl[Formula: see text] have been made by casting from their aqueous solutions. The structure of un-annealed and annealed PVA-YCl3 films was studied using X-ray diffraction (XRD) patterns and Fourier-transform infrared spectroscopy (FTIR). Both FTIR and XRD revealed that the crystalline ratio of the studied samples increased due to the effect of annealing. The effect of annealing on the optical properties has been studied. Dispersion of the refractive index was described using the single oscillator model. The single oscillator energy and the dispersion energy were estimated. The calculated optical band gap of all PVA-YCl3 films was 5.0[Formula: see text]eV. The behavior of ac conductivity showed that the conduction mechanism of PVA-YCl3 films was correlated barrier hopping model. The dielectric constant and dielectric loss index were decreased with the increase of the field frequency. The electric modulus granted a straightforward technique for assessing the dielectric relaxation time. The calculated activation energy obtained from the electric modulus mechanism was 0.172[Formula: see text]eV.
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