Structural characteristics and flammability of low-order coal pyrolysis semi-coke

Abstract

This study focused on the effects of pyrolysis temperature on the structural characteristics and combustion properties of low rank coal. The combustion performance of semi-coke at different temperatures was studied by using low-temperature pyrolysis technology and non-isothermal thermogravimetric analysis. The variation of functional groups and carbon structure was quantitatively analyzed. The results show that the temperature has a significant effect on the semi-coke structure and flammability. In the middle and low temperature pyrolysis stage, the removal of water, volatile matter and functional groups is mainly carried out, and the degree of condensation and graphitization of carbon atoms is not obvious. The semi-coke performance with a pyrolysis temperature of 1023K is close to that of anthracite. The pyrolysis process is accompanied by the destruction of carbonaceous and the formation of mesopores, which affects the combustion performance. As the temperature increases, the flammability of the semi-coke is lowered, and the chemical structure of the semi-coke is a major factor affecting the flammability. The method of Coast-Redfern integration was used to calculate the kinetic parameters of the semi-coke. As the pyrolysis temperature increases, the activation energy of the combustion reaction increases, which is consistent with the trend of combustion performance change.