Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K S Mok,C K Poon,H W Tong

doi:10.1039/dt9720001701

Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K S Mok, C K Poon + Show 1 more

https://doi.org/10.1039/dt9720001701

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Journal: J. Chem. Soc., Dalton Trans.	Publication Date: Jan 1, 1972
Citations: 6

#Central Cobalt #Amine Complexes #Central Cobalt Ion #Hydrolysis Of Cation #Range Of Temperature #Effects Of Ligands #Cobalt Ion #Structural Studies #Octahedral Cobalt #Amine Ligands

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The prepration and characterization of trans-[Co(NH3)4(NCS)Cl]+ cation is described. The kinetics of the aquation and base hydrolysis of this complex cation and those of trans-[Co(cyclam)(NCS)Cl]+ have been studied over a range of temperature. These results are discussed in terms of the influence of nephelaxetic effects of these amine ligands on the central cobalt(III) ion.

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Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand