Structural and magnetic properties of erbium doped nanocrystalline Li–Ni ferrites

Abstract

A series of nanocrystalline Li0.25Ni0.5Fe2.25−xErxO4 (x=0.00, 0.02, 0.06, 0.08, and 0.10) ferrite powders, having a cubic spinel crystal structure and a low value of coercivity, was synthesized by the sol–gel auto-combustion route. The structure, morphology and magnetic properties of the prepared nanoferrites were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the magnetic property measurement system (MPMS). A well-defined single phase spinel structure is confirmed in all the samples by X-ray diffraction analysis. The lattice parameters of the samples increase slightly with increasing the erbium content. The crystallite size of the Er-doped samples is smaller than that of pure Li–Ni ferrite, and decrease regularly in the range of 36.0–14.5nm. It has been observed that the magnetic properties of these ferrites are strongly influenced by the added erbium content. The magnetic measurements indicate that saturation magnetization (Ms) and coercivity (Hc) decrease gradually with the increase of Er content in the lattice.