Abstract
The overall stability constants of zinc bromide and iodide complexes in DMSO—water and those of zinc chloride, bromide and iodide in DMF—water mixtures have been determined potentiometrically at mole ratios about 0.2–1 for the organic solvents at 25°C and in a 0.5 M ammonium perchlorate ionic medium. The complex formation is much stronger in DMF and its mixtures than in DMSO and the log βs are generally higher in solvent mixtures than those expected from the values measured in the pure components.
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