Abstract
AbstractThe morphology and growth rates of crystallized fractions of poly(3,3‐dimethyloxetane) covering the range Mn = 18500 to Mn = 130000 were studied by polarized light microscopy at crystallization temperatures from 24 to 44°C. It was found that the growth rate is linear and only spherulites are formed in the temperature range examined. The growth rate‐temperature coefficient was analyzed by using nucleation theory. The usual plots are linear in the whole range of crystallization temperatures, and the comparison between dilatometric and growth data revealed that the overall rate‐ and growth rate‐temperature coefficients are approximately the same.
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