Abstract
Structure of molecular complexes of zinc(II)tetraphenylporphyrin with 4-dimethylaminopyridine and 4-methoxyaniline has been studied by X-ray diffraction analysis. 4-Dimethylaminopyridine is coordinated almost perpendicular to the porphyrin cycle plane, whereas 4-methoxyaniline is coordinated at lower dihedral angle. The hybridization of aniline nitrogen atom in the crystal depends on donor-acceptor properties and the volume of the substituents in the aromatic ring.
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