Abstract
The processes of the formation of a molecular complex of zinc(II) tetraphenylporphyrin with amines and aniline and pyridine derivatives are studied via calorimetry and IR spectroscopy. Standard thermodynamic characteristics of the formation of zinc(II) tetraphenylporphyrin complexes with ligands are obtained, and the centers of interaction between ligands and porphyrin are determined. In the case of amino derivatives of pyridine, interaction with zinc(II) tetraphenylporphyrin proceeds on amino groups.
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