Abstract
Some complexes of the chlorides and bromides of manganese(II), iron(II), cobalt(II), nickel(II) and copper(II) with nicotinamide and nicotinic acid have been prepared. These complexes have stoichiometryML 2X2 whereM is a metal ion,L is an organic ligand andX is a halide ion. Spectral and magnetic properties indicate that these compounds have octahedral polymeric structures. The decomposition of the complexes was studied by thermogravimetry and differential thermal analysis. In only one instance was a decomposition product of the formulaMLX2 obtained. Its structure was also octahedral.
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