Abstract
Irreversible solid-state conversion of pencil shaped Na coordination polymer nanorods, prepared by sonochemical procedure, to nanoparticles of corrugated tape silver polymer has been observed upon mechanochemical reaction of compound [Na(μ2-Hdcpa)(μ3-dcpa)]n (1), [Hdcpa=2,4-dichlorophenoxyacetic acid] with AgNO3. These nanostructures were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), IR spectroscopy and elemental analyses. Thermal stability of these samples was also studied by thermo gravimetric (TG) and differential thermal analyses (DTA).
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