Abstract
Abstract We report a new matrix for single molecule spectroscopy: terrylene doped into benzophenone. The peculiarity of this matrix consists of its polymorphism. Single terrylene molecules were detected in the polycrystalline phase of the benzophenone host. In the glassy phase of the matrix, single molecules were not resolved. An upper limit for the homogeneous width of the terrylene molecules in the glassy phase was obtained from hole-burning experiments. Total luminescence spectra in both amorphous and crystalline phase of bulk samples were measured.
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