Abstract
Complex formation between water-soluble cobalt(II) phthalocyaninates and 1,4-diazabicyclo[2.2.2]-octane has been studied. The formation of the 1: 1 molecular complex and the 2: 1 sandwich-type dimers has been confirmed. The sandwich-type dimers and the J-aggregates involving the peripheral groups of the macrocycle are formed in ethanol medium. Stability constants of the molecular complexes have been determined, and the effect of size of the peripheral substituents on the dimeric structures stability has been elucidated.
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