Abstract
AbstractWe have developed a conceptually and methodologically novel self‐assembled multilayer nickel nanoparticle (NP) catalyst – sulfur‐modified gold‐supported Ni NPs (SANi) – for organic synthesis. The SANi catalyst was easily prepared through a three‐step procedure involving simultaneous in situ metal NP and nanospace organization. This unique method does not require any conventional preformed template for immobilizing and stabilizing NPs. SANi catalyzes carbon‐carbon bond‐forming cross‐coupling, Kumada coupling, and Negishi coupling reactions under ligand‐free conditions and can be used repeatedly for these reactions. Physical analysis of SANi showed that the active species in these reactions are self‐assembled multilayer zerovalent Ni NPs with a size of ∼3 nm.magnified image
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
