Abstract
Second order interference effects have been incorporated in the calculation of the quasifree rotation absorption coefficient of diatomic molecules in non polar solvents. These effects are analysed in the calculation of the fundamental band infrared spectra of HCl and DCl in liquid Xe at T = 205 K, and the results are compared with the experimental data of Knudtson and Weitz [J. Chem. Phys. 83, 927 (1985)]. Second order interference effects show relevant contributions both in the spectral regions near to the maximum of the P and R branches, and in the PR inter-branch region.
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