Abstract

We demonstrated Schottky-barrier solar cell using layer-structured semiconductor tungsten disulfide (WS2) nanofilm (NF) as the photo-active material. WS2 NFs were synthesized by chemical-vapor-deposition initiated on the surface of tungsten. The growth of WS2 NF was confirmed by Raman signature peaks representing active modes of E12g (351.5 cm−1) for in-plane and A1g (420.1 cm−1) for out-of-plane atomic vibrations, respectively. The ITO/WS2/Au Schottky-barrier solar cell was demonstrated by a layer-enabled assembling process, showing a photo-conversion efficiency of 1.7% and effective photon absorption in the wavelength range of 350 nm–950 nm. The Mott-Schottky characteristic suggests low density of bulk and interface defects in WS2 NF attributed to surfaces with negligible amount of dangling bonds which is the essential nature of layered semiconductors.

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