Abstract

PbO–Sb 2O 3–B 2O 3 glasses mixed with different concentrations of TiO 2 (ranging from 0 to 1.5 mol.%) were synthesized. The samples are characterized by X-ray diffraction, scanning electron microscopy and DSC techniques. A variety of properties, i.e. optical absorption, photoluminescence, infrared, ESR spectra, magnetic susceptibility, photo-induced birefringence (PIB) and dielectric properties (constant ɛ′, loss tan δ, a.c. conductivity σ ac over a wide range of frequency and temperature) of these glass–ceramics have been explored. The analysis of these results indicated that Ti ion surrounding ligands play principal role in the observed PIB and the sample crystallized with 0.8 mol.% of TiO 2 is the most suitable for the applications in non-linear optical devices.

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