Role of Sn(II) in Mediating the Formation and Organization of a Langmuir Monolayer.

Abstract

The influence of the Sn(II) ion on the formation and morphology of an arachidic acid (AA) monolayer was investigated using Langmuir film formation technology, pressure-area (Π-A) isotherm measurements, and Brewster angle microscopy (BAM). Our findings indicate that AA Langmuir monolayers exhibit organization that depends on subphase pH and Sn2+ concentration. There are multiple equilibria that are relevant to the complexation of AA monolayers, and the balance of Sn(OH)n equilibria and Sn(AA)n equilibria gives rise to unusual monolayer structural effects. With Sn2+ in the subphase, the AA monolayer exhibits an isotherm characterized by the absence of a collapse point and with a pH-dependent change in isotherm shape not consistent with the formation of an ordered solid phase. The amphiphile headgroup equilibrium mediates the absence of collapse seen experimentally and the ability of the monolayer to retain organization at a surface pressure of ca. 70 mN/m. BAM images show that the morphology of the monolayer depends on the Sn2+ concentration, consistent with several species of Sn(AA)n, where n = 1, 2, or 3, contributing to the overall monolayer order.