Removal of reactive black 5 dye using zero valent iron nanoparticles produced by a novel green synthesis method

Abstract

Purpose The purpose of this paper is to analyze zero valent iron nanoparticles (NZVIs) by a novel green method, taken from Thymus vulgaris (TV) plant extract, were synthesized and applied to degrade reactive black 5 (RB5) azo dye. Design/methodology/approach The optimum conditions for the highest removal of RB5 dye were determined. Characterization of NZVIs was done by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The NZVIs were used for the removal of dye RB5, and the parameters affecting were discussed like pH, initial concentration, contact time and NZVIs dosage. Findings The characterization results of NZVIs by SEM, TEM, FTIR and XRD show that polyphenols, organic acids and proteins reduce not only the green synthesis of NZVIs but also the aggregation of nanoparticles. The maximum dye removal efficiency of 99.6 per cent occurred at pH 4, NZVIs dose of 600 mg/L, and contact time of 5 min. The adsorption of RB5 dye onto the NZVIs surface and scavenging of the azo bond (−N = N) by the strong reduction of NZVIs were the proposed mechanisms for dye removal. The application of NZVIs to treat wastewater containing reactive dye shows high degradation efficiency. Research limitations/implications The findings may greatly benefit the application of the NZVIs taken from Thymus vulgaris (TV) in the fields of dye adsorption. Practical implications The present study is novel because it incorporated the morphological and structural properties of the synthesized NZVIs using a native plant of Iran and studied the capability of green-synthesized NZVIs to remove RB5 as a water contaminant. Social implications The native plant presented here can be developed for reduced environmental pollution before discharge to accepted water. Originality/value The NZVIs is prepared via green-synthesized method, which is prepared with leaves of TV. There are two main innovations. One is that the novel NZVIs is prepared successfully by native plant via green-synthesized method. The other is that the optimized conditions were obtained for the removal of RB5 dye as a water contaminant. Furthermore, to the best of our knowledge, no study has ever investigated the removal of RB5 by NZVIs produced using a native plant in Iran.