Removal of endosulfan from water by municipal waste incineration fly ash-based geopolymers: Adsorption kinetics, isotherms, and thermodynamics

Abstract

Alkali-activated municipal waste incineration fly ash (MWFA)-based geopolymers (GPA, GPB, and GPC) were synthesized under different sodium silicate to sodium hydroxide (SS/SH) ratios. The geopolymers were applied in the removal of endosulfan, a persistent and toxic chemical, from water. The adsorbents were characterized by XRD, SEM-EDX, and FTIR. Variation of SS/SH ratios resulted in morphologically distinguishable geopolymers with different compositions. The adsorption equilibrium data were best described by the Langmuir isotherm. The maximum adsorption capacities increased with an increase in SS/SH ratios in the order 1.87, 15.89, 16.97, and 20.01 mg/g for MWFA, GPA, GPB, and GPC, respectively. The kinetic data were best described by the pseudo-first-order model wherein the adsorption rate (k1) was independent of the SS/SH ratios and the geopolymer composition. The thermodynamic parameters, that is, enthalpy (∆H > 0), Gibbs free energy (∆G < 0), entropy (∆S > 0), and activation energy (Ea > 0), show that the processes were endothermic, spontaneous, physical (Ea and ∆H < 40 kJ/mol), and entropy-driven. Alkalination was beneficial since the geopolymers had a higher adsorption capacity (∼8–10 times) and affinity for endosulfan (∼30 times) than the precursor material (MWFA). The adsorption mechanism entailed electrostatic interactions and hydrogen bonding. The MWFA-based geopolymers are, therefore, potential alternative low-cost adsorbents for the removal of endosulfan from water and a strategy for the valorization of MWFA.