Recent progress of gold nanostructures and their applications.

Abstract

For noble metals, such as gold (Au) and silver (Ag), it is well-known that surface plasmons of their nanocrystals have significant spatial confinement and propagation loss due to the strong damping effect and the scattering between the plasmons and phonons. Noble metal nanostructures are usually referred to as "plasmonic nanostructures" in many studies. Based on the resonance effect of surface plasmons, the electromagnetic field can be localized on the subwavelength scale, which induces a booming new field of nanophotonics. Among the various nanostructures, Au nanostructures have received extensive attention both in fundamental research and technological fields due to their unique localized surface plasmon characteristics. These characteristics include strong optical extinction, near-field enhancement, and far-field scattering. By changing either the morphological parameters or the surrounding medium of nanostructures, the localized surface plasmon resonance (SPR) of Au nanostructures can be tuned in a large spectral region from visible to near infrared (Vis-NIR) wavelength. Corresponding to the experimental research, there are several numerical techniques that enable modeling the optical characteristics of Au nanostructures in different shapes and assemblies. The most popular technique is the finite-difference time-domain (FDTD) method for modeling various nanostructures and nanoscale optical devices. The accuracy of the computational models has been proven by reliable experimental data. In this review, we focused on Au nanostructures of different morphologies, such as nanorods, nanocubes, nanobipyramids and nanostars. Then combined with FDTD simulations, we described the effect of morphological parameters and the surrounding medium on the SPR properties of Au nanostructures. More and more achievements indicate that the surface plasmon effect is promising in many technical fields. In the last part, we summarize some typical applications of plasmonic Au nanostructures, such as high sensitivity sensors, photothermal conversion with hot electron effects and photoelectric devices, as well as plasmonic nanolasers.