Reactivity of Sulfur and Nitrogen Compounds of FCC Light Cycle Oil in Hydrotreating over CoMoS and NiMoS Catalysts

Abstract

NiMoS and CoMoS catalysts were synthesized and applied to hydrotreating (HDT) of FCC light cycle oils (FCC-LCO) in an autoclave batch reactor at 613 K and 8.6 MPa H2. The S and N compounds in LCO were classified into four and three groups, respectively, in terms of the HDT reactivity. The individual and the competitive reactivities of the S and N compounds in the HDS and the HDN were investigated over the conventional CoMoS and NiMoS catalysts using S and N model compounds (dibenzothiophene, DBT, and carbazole, CBZ). In the HDS of DBT, both the direct desulfurization (DDS) and pre-hydrogenation pathway (HYD) were found to proceed, whereas the HYD pathway was favored for the HDN of CBZ. As a result, the NiMoS catalyst that facilitates the HYD pathway showed better activity in the HDN of LCO than the CoMoS (k = 10.20 × 10−2 vs. 1.80 × 10−2 h−1). Indeed, the HDS of LCO over the NiMoS was more favorable than that over the CoMoS catalyst (k = 4.3 × 10−1 vs. 3.6 × 10−1 h−1).