Abstract
The diazotisation of 1-methyl-4-aminopyridinium perchlorate in 0.25–5.00M-perchloric acid is of first order in both the amine and nitrous acid. The rate coefficients increase with an increase in the concentration of perchloric acid and sodium perchlorate. In perchloric acid solutions whose ionic strength is maintained constant by the addition of sodium perchlorate the rate coefficients of the diazotisation of 1-methyl- and 1-methoxy-4-aminopyridinium perchlorate show a rectilinear dependence on the ho parameter of the medium. It is suggested that the reaction involves an initial interaction between the nitrosating agent and the heteroaromatic nucleus of the 1-methyl- or the 1-methoxy-4-aminopyridinium ion. pKa Values are recorded.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
