Raman selection rules and tensor elements for PMN–0.3PT single crystal

Abstract

AbstractSelection rules were put forward theoretically and Raman tensor elements experimentally determined for PMN–0.3PT single‐crystal. Such a body of information was then employed to evaluate local domain orientation in a relaxor‐based PMN–0.3PT material by means of polarized microprobe Raman spectroscopy. The dependence of Raman spectra upon crystal rotation under different polarized probe configurations was experimentally confirmed by collecting the intensity variation of selected Raman modes on Euler's angle rotation in a poled single‐crystal. The periodicity of relative Raman intensity of selected Raman bands revealed symmetry properties. Upon exploiting such properties and with the knowledge of the Raman tensor elements from the Ag and Eg vibrational modes, a viable path becomes available to determine domain texture in relaxor‐based PMN–PT materials with high spatial resolution. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)