Abstract
A recent study suggests the existence of highly polar and nonpolar long-range Rydberg molecules under temperature and density conditions representative of those found in atomic Bose-Einstein condensates. The electronic wave functions of these Rydberg molecules are characterized by an elliptically shaped nodal structure. We use a combination of quantum and semiclassical methods to explore this unique nodal structure and its correlations with the Born-Oppenheimer potential curves of the molecules. We demonstrate a special ``quasiseparability'' that arises in elliptic coordinates at certain internuclear separations and give a semiclassical interpretation of this in terms of quantized Einstein-Brillouin-Keller orbits.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
