Abstract
SynopsisWe report on the observation of long-range Cs2 Rydberg molecules consisting of a p-state Rydberg atom and a ground-state atom. Two types of molecular states are visible in the photoassociation spectra: states bound purely by triplet s-wave scattering and states bound by mixed singlet-triplet s-wave scattering. An effective Hamiltonian including s-wave scattering pseudopotentials, the hyperfine interaction of the ground-state atom, and the spin-orbit interaction of the Rydberg atom reproduces the experimental observations. The detailed analysis reveals the important role of singlet scattering in long-range Rydberg molecules and yields an effective singlet s-wave scattering length for low-energy e−-Cs collisions.
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