Abstract
ABSTRACT CuO – CeO2/CaO composite oxide was prepared for mine special environment in this study through the solid-phase impregnation method using the traditional CuO – CeO2 and CaO as the CO catalyst and the modified additive, respectively, to address the CO poisoning in underground coal mines effectively. Influences of CaO mass on the ablation performances of CuO – CeO2/CaO were investigated under dynamic and static CO/CO2 heat capture experiments using the self-made activity testing device. Results demonstrated that adding CaO can realize in-situ adsorption of CO2, thus increasing utilization of oxygen and promoting CO catalysis of the prepared composite oxide. The performances of CuO – CeO2/0.15CaO was the best when the dosage of CaO was 15 wt%. The CO reaction capacity and CO2 adsorption capacity reached 1.17 and 0.56 mg·g−1, respectively. The thermodynamic properties and microstructural characteristics of the synthesized composite oxide were systematically investigated utilizing a simultaneous thermal analyzer, Fourier infrared spectrometer, XRD diffractometer, and scanning electron microscope. Adding CaO can also improve the thermostability of the composite oxide and increase active sites on the sample surface. The emergence of adsorption products Ca(OH)2 and CaCO3 proves that CuO – CeO2/CaO has relatively good moisture and CO2 adsorption. Analysis of the ablation performances of CO/CO2 after coal combustion with CuO – CeO2/CaO revealed that the prepared composite oxide not only effectively lowers CO concentration after coal combustion but also adsorbs CO2 during catalysis and decreases smoke risks. The released CO concentration from coal combustion after 240 s can be decreased to less than 0.0024% when the mass ratio of CuO – CeO2/0.15CaO and coal is 1:3. The ablation results confirm that, as a new type of composite material, the CuO – CeO2/0.15CaO composite oxide can provide a new technical means for CO control in coal mines.
Published Version
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